Health Dictionary
Reliable, easy-to-read patient information on common medical conditions — written in plain language, free of jargon, and grounded in current evidence. Browse the most frequent diagnoses, understand what they mean for everyday life, and learn which steps and questions help you have a focused conversation with your doctor.
Stieglitz rearrangement
Introduction
The Stieglitz rearrangement is a rearrangement reaction of a trityl hydroxylamine Ar3CNHOH to a triaryl imine [1] [2]. The reaction is related to the Beckmann rearrangement as both reaction involve a carbon to nitrogen shift.
References
- ↑ Julius Stieglitz, Paul Nicholas Leech (1914). “The molecular Rearrangement of Triarylmethyl-Hydroxylamines and the Beckamnn Rearrangement of Ketoximes”. Journal of the American Chemical Society. 36 (2): 272–301. doi:10.1021/ja02179a008.
- ↑ Bert Allen Stagner (1914). “The molecular Rearrangement of Triarylmethyl-Hydroxylamines”. Journal of the American Chemical Society. 36 (2): 2069–2081. doi:10.1021/ja02267a018.